Refine your search
Co-Authors
Journals
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z All
Krishna Reddy, V.
- Direct and Derivative Spectrophotometric Determination of Chromium(VI) in Microgram Quantities Using 5-Bromo Salicylaldehyde Isonocotinoyl Hydrazone (5-BrSAINH)
Abstract Views :268 |
PDF Views:2
Authors
Affiliations
1 Department of Chemistry, Sri Krishnadevaraya University, Anantapur, 515003 (A.P), IN
1 Department of Chemistry, Sri Krishnadevaraya University, Anantapur, 515003 (A.P), IN
Source
Asian Journal of Research in Chemistry, Vol 6, No 7 (2013), Pagination: 667-670Abstract
A highly sensitive and selective spectrophotometric method was developed for the determination of trace amount of chromium (VI) in aqueous DMF medium. The chromate ion forms a light brown colored complex with 5-Bromo salicylaldehyde isonocotinoyl hydrazone (5-BrSAINH) in an acidic buffer of pH 6.0. The complex has an absorbance maximum at 430nm, was stable for more than 72 hours. Beer's law is obeyed in the range 0.16 - 3.90 μgml-1. The molar absorptivity and sandell's sensitivity of the colored solution were found to be 2.0 x 104 L.mol-1cm-1 and 2.6 X 10-3 μgcm-2, respectively. The light brown colored complex has 1:1 (Chromium (VI) - 5BrSAINH) Stoichiometry. The stability constant of the complex was determined as 1.40 X 106 by Job's method. The effect of foreign ions on the determination was studied. A sensitive and selective first and second order derivative spectrophotometry has also been proposed for the determination of Cr (VI). The interference of various cations and anions were studied. The developed methods were successfully employed in the determination of Cr (VI) in soil and standard steel samples.Keywords
Spectrophotometry, 5-BrSAINH, Determination of Chromium (VI), Soil Samples, Standard Steel SamplesReferences
- IARC [1990] (1990-11-05) Volume 49: Chromium, Nickel and Welding, ISB 92-832-1249-5.
- Arya S. P. and Bansal A., Spectrophotometric determination of chromium(VI) with ferron, Fresenius' Journal of Analytical Chemistry, 348(11), 772-775 (1994).
- Wang C F, Chin C J, Luo S K and Men L C (1999) Determination of chromium in airborne particulate matter by high resolution and laser ablation inductively coupled plasma mass spectrometry. Anal Chim Acta 389: 257 .
- Gurley H and Wallschlaeger D (2001) Determination of chromium (III) and chromium (VI)using suppressed chromatography inductively coupled plasma mass spectrometry. J Anal Atom Spectrum 16: 926.
- Makishima A, Kobayashi K and Nakamura E (2002) Determination of Chromium, Nickel, Copper and Zinc in Milligram Samples of Geological Materials, Geostandards newsletter. 26: 41.
- Peng T Y, Jiang Z C, Hu B and Liao Z H (1999) Catalytic Spectrophotometric Determination of Chromium. Fresen J Anal Chem 364: 551.
- Imran A, Hassan Y A (2002) Speciation of arsenic and chromium metal ions by Reversed phase high performance liquid chromatography. Chemosphere 48: 275.
- Balasubramanian S, Pugalenthi V (1999) Determination of total chromium in tannery waste water by inductively coupled plasma-atomic emission spectrometry, flame atomic absorption spectrometry and UV–vis spectrophotometric methods, Talanta 50: 45.
- Monteiro M I C, Fraga I C S, Yallouz A V, Oliveira N M M , Ribeiro S H (2002) Determination of total chromium traces in tannery effluents by electrothermal atomic absorption spectrometry, flame atomic absorption spectrometry and UV–vis spectrophotometric methods. Talanta 58: 629.
- Sreevani I Raveendra Reddy P, Krishna Reddy V , A Rapid and Simple Spectrophotometric Determination of traces of Chromium (VI) in Waste Water Samples and in Soil samples by using 2- Hydroxy, 3-Methoxy Benzaldehyde Thiosemicarbazone (HMBATSC), IOSR Journal of Applied Physics 3(1) (Jan. - Feb. 2013), PP40:45.
- Veena K and Narayana B, A New Facile and Sensitive Method for the Spectrophotometric Determination of Chromium, Eurasian Journal of Analytical Chemistry, 3(3), 2008.
- Jamaluddin Ahmed M and. Reazul Haque M, A Rapid Spectrophotometric Method for the Determination of chromium in Environmental Samples using Bis (salicylaldehyde) orthophenylenediamine, Research Journal of Chemical Sciences, 1 (1) April (2011).
- Revanasiddappa H . D, Kiran kumar T.N, A highly sensitive spectrophotometric determination of chromium using Leuco Xylene cyala FF, Talanta 60(1),2003.
- Parkash R, Bansal R, Kaur A, Rehani SK, Malachite green as a reagent for detection and spectrophotometric determination of Chromium (VI),Talanta 38(10),1991.
- Katsumi G,Hiroki T, Mitsuko O, Masaichi N , Spectrophotometric determination of aluminium with ferron and a quaternary ammonium salt, Talanta 21(3), 1974.
- Efficiency of Stream Processing Engines for Processing BIGDATA Streams
Abstract Views :184 |
PDF Views:0
Authors
Affiliations
1 Department of Computer Science and Engineering, K L University, Green Fields, Vaddeswaram, Guntur - 522502, Andhra Pradesh, IN
1 Department of Computer Science and Engineering, K L University, Green Fields, Vaddeswaram, Guntur - 522502, Andhra Pradesh, IN
Source
Indian Journal of Science and Technology, Vol 9, No 14 (2016), Pagination:Abstract
Background/Objectives: In this paper, there are real-time stream & big data stream applications running on a large amount of clusters & live migration of data using intensive & interactive tasks. Methods/Statistical Analysis: Traditionally, there are many stream processing engines which are going to manage the processing data in this streaming scenario, ongoing stream processing the data must be handle due to faults & stragglers within a second-scale latency. At present, there are efficient stream processing engines which can avoid these faults & stragglers by using the stream processing engines like APACHE SPARK & APACHE FLINK. Findings: In the real-time data stream processing there are some problem occurrences while processing the data, those are data latency, fault-tolerance, mutable data-sets and more stragglers. To avoid all these issues there is an efficient stream processing engines with additional added mechanisms like dolly retreat mechanism for avoiding stragglers and process data efficiently. Application/Improvements: Now a day’s demand for stream processing is increasing a lot which may be real-time streaming or normal cluster data transformation. Data has to be processed fast, so that companies are integrating these stream processing engines to changing their business conditions effectively in realtime for analyze their data more effectively with help of Fast Stream Processing Engines.Keywords
Fault-Tolerance, RDD, Second-Scale Latency and Immutable Datasets, Stragglers- Performance Analysis of Load Balancing Algorithms in Cloud Computing Environment
Abstract Views :188 |
PDF Views:0
Authors
Affiliations
1 Department of CSE, K L University, Vaddeswaram, Guntur - 522502, Andhra Pradesh, IN
1 Department of CSE, K L University, Vaddeswaram, Guntur - 522502, Andhra Pradesh, IN
Source
Indian Journal of Science and Technology, Vol 9, No 18 (2016), Pagination:Abstract
Background/Objectives: In this paper, the performance of cloud computing system is greatly influenced by the problem of load balancing. The complexity class of the load balancing problem with respect to the complexity class belongs to the NP-system complete which involves intensely huge search space with huge number of potential solutions and also to find the optimal solution, it takes longer time. Based on these circumstances, there is no methodology to solve the problem. Methods/Statistical Analysis: In the cloud, we can find a near optimal solution, within a brief span of time. In this situation IT practitioners are focusing on heuristic methods. This paper proposes a multi objective load balancing in a cloud computing environment. Findings: This model can be applied to schedule the tasks on to the distinct data center resources. Ant Colony Optimization (ACO) algorithm is considered to know the optimal solution. Application/Improvements: Experimental results show that proposed model exceeds existing models in terms of reduction in energy consumption, improving pool utilization, minimizing the number of active nodes.Keywords
Ant Colony Optimization (ACO), Cloud Computing, FCFS Algorithm, Genetic Algorithm.- Solar Photo Voltaic Power Generation:An Indian Perspective
Abstract Views :115 |
PDF Views:0
Authors
Affiliations
1 Dept of Mechanical Engineering, Krishna Chaitanya Institute of Technology & Sciences, Markapur, A.P, IN
2 P.R.Poly Technical College, Giddalur, A.P, IN
1 Dept of Mechanical Engineering, Krishna Chaitanya Institute of Technology & Sciences, Markapur, A.P, IN
2 P.R.Poly Technical College, Giddalur, A.P, IN